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Sodium acrylate

目录号 : GC25941

Sodium acrylate is a metal salt that can be prepared by an acid-base reaction between sodium hydroxide and acrylic acid.

Sodium acrylate Chemical Structure

Cas No.:7446-81-3

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产品描述

Sodium acrylate is a metal salt that can be prepared by an acid-base reaction between sodium hydroxide and acrylic acid.

[1] Liu L, et al. Angew Chem Int Ed Engl. 2019 Nov 4;58(45):16307-16313.

Chemical Properties

Cas No. 7446-81-3 SDF Download SDF
分子式 C3H4O2.Na 分子量 94.04
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1 mg 5 mg 10 mg
1 mM 10.6338 mL 53.1689 mL 106.3377 mL
5 mM 2.1268 mL 10.6338 mL 21.2675 mL
10 mM 1.0634 mL 5.3169 mL 10.6338 mL
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Research Update

Microwave assisted synthesis of guar gum grafted Sodium acrylate/cloisite superabsorbent nanocomposites: reaction parameters and swelling characteristics

Int J Biol Macromol 2014 Apr;65:500-8.PMID:24530336DOI:10.1016/j.ijbiomac.2014.02.008.

In this study, superabsorbent nanocomposites of guar gum grafted Sodium acrylate have been synthesized via both microwave and conventional techniques. The reaction parameters of both techniques were optimized and the microwave assisted method was proved to have higher grafting yield with lesser time of reaction as compared to the conventional method. X-ray diffraction and scanning electron microscopy analyses revealed that cloisite was exfoliated and uniformly dispersed in guar gum grafted Sodium acrylate matrix. The results show that introducing cloisite into the guar gum grafted Sodium acrylate network improved the swelling capability and the swelling rate of the superabsorbent nanocomposite was found to be enhanced at an optimal loading of 10% cloisite. The nanocomposites showed high water absorbency within a wide pH range. Preliminary studies on crystal violet dye removal showed promising results.

Degradation of a Sodium acrylate oligomer by an Arthrobacter sp

Appl Environ Microbiol 1993 May;59(5):1555-9.PMID:8517751DOI:10.1128/aem.59.5.1555-1559.1993.

Arthrobacter sp. strain NO-18 was first isolated from soil as a bacterium which could degrade the Sodium acrylate oligomer and utilize it as the sole source of carbon. When 0.2% (wt/wt) oligomer was added to the culture medium, the acrylate oligomer was found to be degraded by 70 to 80% in 2 weeks, using gel permeation chromatography. To determine the maximum molecular weight for biodegradation, the degradation test was done with the hexamer, heptamer, and octamer, which were separated from the oligomer mixture by fractional gel permeation chromatography. The hexamer and heptamer were consumed to the extents of 58 and 36%, respectively, in 2 weeks, but the octamer was not degraded. Oligomers with three different terminal groups were synthesized to examine the effect of the different terminal groups on biodegradation, but few differences were found. Arthrobacter sp. NO-18 assimilated acrylic acid, propionic acid, glutaric acid, 2-methylglutaric acid, and 1,3,5-pentanetricarboxylic acid. Degradation of the acrylic unit structure by this strain is discussed.

Swelling behavior of poly(Sodium acrylate) gels crosslinked by aluminum ions

Colloids Surf B Biointerfaces 2004 Nov 15;38(3-4):209-12.PMID:15542327DOI:10.1016/j.colsurfb.2004.02.022.

The cylindrical poly(Sodium acrylate) gel (SA gel) was synthesized in the glass capillary using aluminum ions as the crosslinker. The swelling ratio of the gel was measured after the repeated exchange of solvent (distilled deionized water, about pH 5.8). The gel exhibited two relaxation processes; at first the gel swells rapidly as exchange of water (the swelling process), then shrinks very slowly (the shrinking process). In order to reveal the microscopic structural change (especially, the formation of hydrogen bonding) by water exchange, attenuated total refraction (ATR) Fourier transform infrared (FT-IR) spectroscopy was applied to the gels with different swelling ratio. The IR absorption peaks of the gel were assigned based on those of poly(Sodium acrylate) aqueous solutions at different pH. On the swelling process, the carboxyl groups were gradually protonated, and the intermolecular hydrogen bonding started to form in the gel with maximum swelling ratio. On the shrinking process, the formation of hydrogen bonding gradually increased with long-time repeated water exchange which resulted in the shrinkage of the gel. Effects of the repeated water exchange on the swelling behavior were discussed in terms of the exchange of counter ions and the formation of hydrogen bonding.

A green approach to prepare silver nanoparticles loaded gum acacia/poly(acrylate) hydrogels

Int J Biol Macromol 2015 Sep;80:177-88.PMID:26123815DOI:10.1016/j.ijbiomac.2015.06.048.

In this work, gum acacia (GA)/poly(Sodium acrylate) semi-interpenetrating polymer networks (Semi-IPN) have been fabricated via free radical initiated aqueous polymerization of monomer Sodium acrylate (SA) in the presence of dissolved Gum acacia (GA), using N,N'-methylenebisacrylamide (MB) as cross-linker and potassium persulphate (KPS) as initiator. The semi-IPNs, synthesized, were characterized by various techniques such as X-ray diffraction (XRD), thermo gravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy. The dynamic water uptake behavior of semi-IPNs was investigated and the data were interpreted by various kinetic models. The equilibrium swelling data were used to evaluate various network parameters. The semi-IPNs were used as template for the in situ preparation of silver nanoparticles using extract of Syzygium aromaticum (clove). The formation of silver nanoparticles was confirmed by surface plasmon resonance (SPR), XRD and transmission electron microscopy (TEM). Finally, the antibacterial activity of GA/poly(SA)/silver nanocomposites was tested against E. coli.

Formation and destruction of hydrogen bonds in gels and in aqueous solutions of N-isopropylacrylamide and Sodium acrylate observed by ATR-FTIR spectroscopy

J Colloid Interface Sci 2007 Aug 1;312(1):14-20.PMID:17547921DOI:10.1016/j.jcis.2006.07.046.

In this paper, the formation and destruction of hydrogen bonds in gels and in aqueous solutions of N-isopropylacrylamide (NIPA) and Sodium acrylate (SA) were studied using Fourier transform infrared (FTIR) spectroscopy with attenuated total reflection (ATR). Aqueous solutions of NIPA and SA monomers with different pHs were prepared, and the ATR-FTIR spectra were obtained immediately after preparing the solution and after having been stored at room temperature for 6 months. It was found that the IR spectra evidently changed after 6 months due to polymerization, and the viscosity of a solution in the lowest pH system increased with time and finally the solution became a gel. The detailed analysis of the IR spectra indicated that the network of the gel was formed by the formation of hydrogen bonds (without crosslinker). Moreover, this physical gel exhibited the re-swelling transition by increasing the pH of solvent. The transition was caused by the destruction of hydrogen bonds due to the dissociation of carboxyl groups, which was also confirmed by the IR spectroscopy.